BIP! Finder - NH···π Interactions Stabilize the Most‐Hindered Rotamer of the(S)‐Tyrosinato Side Group in Bis[(S)‐tyrosinato](diamine)cobalt(III) Complexes: An NMR Spectroscopic and DFT Study

2005 • NH···π Interactions Stabilize the Most‐Hindered Rotamer of the(S)‐Tyrosinato Side Group in Bis[(S)‐tyrosinato](diamine)cobalt(III) Complexes: An NMR Spectroscopic and DFT Study

Authors: Miodragović Đenana U., Vitnik, ZJ, Milosavljević, Slobodan M., Malinar, M.J., Juranić, Ivan O.

Venue: European Journal of Inorganic Chemistry

Type: Publication

Abstract: AbstractConformational analysis based on an analysis of the vicinal α‐ and β‐proton coupling constants of (S)‐tyrosinato ligandsin diastereomers of a bis[(S)‐tyrosinato](1,3‐diaminopropane)cobalt(III) complex is used to calculate the mol fractions of the three most stable rotamers (t, g, h) of the (S)‐tyrosinato ligand’s side groups in D2O solution. The results of this conformational analysis indicate a population increase in the sterically least favorable rotamer h in diastereomers of C1‐molecular symmetry (complexes 5 and 6)... (read more)

Topics: Stereochemistry Crystallography

DOI: 10.1002/ejic.200400873

BIP! social metrics: 0 3
External links: Crossref OpenAIRE

BibTex PDF

Topic-specific impact indicators

Popularity:
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
Influence:
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
Citation Count:
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
Impulse:
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.