BIP! Finder - Investigation of the effect of the aminocarboxylato chelate conformation on the optical activity of the cis(NO2),trans(NH2) -bis(aminocarboxylato)dinitrocobalt/ate(III) isomers

1988 • Investigation of the effect of the aminocarboxylato chelate conformation on the optical activity of the cis(NO2),trans(NH2) -bis(aminocarboxylato)dinitrocobalt/ate(III) isomers

Authors: Juranić, N., Malinar, M.J., Radivojša, P.N., Zarić, Snežana D., Vučelić, D., Vučić, M., Ćelap, M.B.

Venue: Polyhedron

Type: Publication

Abstract: Abstract In the cis (NO 2 ), trans (NH 2 )-bis(aminocarboxylato) dinitrocobalt/ate(III) isomers, containing glycinato, S-alaninato, S- n -valinato, S-valinato, S- n -leucinato, S-leucinato, S- i -leucinato and S-arginine ligands, respectively, it was found that in the Δ-isomers circular dichroic spectra are determined by the configurational contribution to the optical activity. This is connected in the case of optically active ligands with the chair conformation of the chelate rings and the equatorial position of the ring side group. In the Δ... (read more)

Topics: Stereochemistry Crystallography

DOI: 10.1016/s0277-5387(00)81203-6

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External links: Crossref OpenAIRE

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