BIP! Finder - Transition metal complexes with thiosemicarbazide-based ligands. Part XLI. Two crystal structures of cobalt(III) complexes with salicylaldehyde S-methylisothiosemicarbazone and theoretical study on orientations of coordinated pyridines

2001 • Transition metal complexes with thiosemicarbazide-based ligands. Part XLI. Two crystal structures of cobalt(III) complexes with salicylaldehyde S-methylisothiosemicarbazone and theoretical study on orientations of coordinated pyridines

Authors: Bogdanović, Goran, A., Medakovic, V.B., Vojinović, Ljiljana, S., Ćešljević, V.I., Leovac, Vukadin, M., Spasojevic - de Biré, Anne, Zarić, S.D.

Venue: Polyhedron

Type: Publication

Abstract: Two compounds, [Co-III(L)(py)(3)][Co-II(PY)Cl-3]. EtOH and [Co-III(L)(PY)(3)]I-3 (H2L = salicylaldehyde S-methylisothiosemicarbazone, py = pyridine), were synthesized and the crystal structures deter-mined by single-crystal X-ray diffraction. In both structures the geometries of the cation are very similar to a thiosemicarbazide-based ligand coordinated in the mer configuration. The axial pyridines are in mutual perpendicular orientation. the angles between the planes being 85.3(2) and 82.5(2)degrees. The plane of the equatorial pyridine is til... (read more)

Topics: Crystallography Stereochemistry

DOI: 10.1016/s0277-5387(01)00819-1

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