BIP! Finder - Palladium(II) complexes with R2edda-derived ligands. Part II. Synthesis, characterization and in vitro antitumoral studies of R2eddip esters and palladium(II) complexes

2009 • Palladium(II) complexes with R2edda-derived ligands. Part II. Synthesis, characterization and in vitro antitumoral studies of R2eddip esters and palladium(II) complexes

Authors: Bojana B. Zmejkovski, Goran N. Kaluderovic, Santiago Gómez-Ruiz, Zeljko Zizak, Dirk Steinborn, Harry Schmidt, Reinhard Paschke, Zorica Juranić, Tibor J. Sabo

Venue: European Journal of Medicinal Chemistry

Type: Publication

Abstract: New R(2)eddip-type esters (R = cyclopentyl, L3 center dot 2HCl 1.5H(2)O; cyclohexyl, L4 center dot 2HCl center dot H2O) and corresponding palladium(II) complexes, [PdCl(2)L3] (3) and [PdCl2L4]center dot H2O (4), as well as [PdCl2L2] (2: L2 diisobutyl ester of eddip) were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopies and elemental analysis. The crystal structure of L3 center dot 2HCl center dot 2CHCl(3) was resolved and is given herein. The NMR spectroscopy confirmed the presence of two isomers (from three possible) for ea... (read more)

Topics: Stereochemistry

DOI: 10.1016/j.ejmech.2009.02.002

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