BIP! Finder - Comparison of structural features of three new cis-dioxomolybdenum(VI) complexes with 2-hydroxy-1-naphthaldehyde-S-methylisothiosemicarbazone: Possible role of intermolecular interactions on the geometry of the cis-MoO2 unit

2007 • Comparison of structural features of three new cis-dioxomolybdenum(VI) complexes with 2-hydroxy-1-naphthaldehyde-S-methylisothiosemicarbazone: Possible role of intermolecular interactions on the geometry of the cis-MoO2 unit

Authors: Tomić, Zoran D., Kapor, Agneš, Zmiric, Aleksandra, Leovac, Vukadin M., Zobel, Dieter, Zarić, Snežana D.

Venue: Inorganica Chimica Acta

Type: Publication

Abstract: Abstract Three closely related [MoO 2 (L)(ML)] complexes, where L is the 2-hydroxy-1-naphthaldehyde- S -methylisothiosemicarbazone ligand, and ML is EtOH ( I ), Py ( II ) and DMSO ( III ), were synthesized, characterized by NMR and IR spectra, and their X-ray crystal structures were determined. The crystal structure properties of these three closely related complexes were compared. Two cis -Mo–O bond lengths were almost the same in the crystal structure of complexes II and III , while in complex I a significant difference between the two cis ... (read more)

Topics: Crystallography Stereochemistry Geometry

DOI: 10.1016/j.ica.2006.10.026

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