BIP! Finder - Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N′,N′2-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide

2008 • Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N′,N′2-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide

Authors: Filipović, Nenad, Bacchi, Alessia, Lazić, Milan, Pelizzi, Giancarlo, Radulović, Siniša, Sladić, Dušan M., Todorović, Tamara R., Andjelković, Katarina

Venue: Inorganic Chemistry Communications

Type: Publication

Abstract: A new dinuclear complex of Cd(II) with N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide (H2L) was synthesized and its crystal structure determined. The basic structural unit of the complex is the binuclear [Cd-2(H2O)(2)(H2L)(2)](4+) cation, where each cadmium atom is heptacoordinated by two tridentate H2L ligands, by means of the NNO chelating system, and one water molecule. A 12-membered macrocycle is defined at the core of the binuclear cation. The complex showed a pronounced cytotoxic activity to murine melanoma B16 cells and hum... (read more)

Topics: Stereochemistry Crystallography

DOI: 10.1016/j.inoche.2007.10.013

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