2007 • Probing the Mechanism of Carbon−Hydrogen Bond Activation by Photochemically Generated Hydridotris(pyrazolyl)borato Carbonyl Rhodium Complexes: New Experimental and Theoretical Investigations
Authors: Blake, Alexander J., George, Michael W., Hall, Michael B., McMaster, Jonathan, Portius, Peter, Sun, Xue Z., Towrie, Michael, Webster, Charles Edwin, Wilson, Claire, Zarić, Snežana D.
Venue: Organometallics
Type: Publication
Abstract: Fast time-resolved infrared (TRIR) experiments and density functional (DFT) calculations have been used to elucidate the complete reaction mechanism between alkanes and photolytically activated hydridotris(pyrazoly-1-yl)boratodicarbonylrhodium. TRIR spectra were obtained after photolysis of Rh(TP4-tBu-3,5-Me)(CO)(2) in n-heptane, n-decane, and cyclohexane and of Rh(Tp(3,5-Me))(CO)(2) in n-heptane and cyclohexane. Initial photolysis produces a coordinatively unsaturated, 16-electron monocarbonyl species that vibrationally relaxes to an intermedi... (read more)
Topics:  Photochemistry
DOI: 10.1021/om7008217
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External links: Crossref OpenAIRE
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