BIP! Finder - An Fe(III) Complex with the Dianionic form of 2,6-Diacetylpyridine Bis(Acylhydrazone). The Crystal Structure of [Diaqua-2′,2′′′-(2,6-PyridinediyldiEthylidyne)Dioxamohydrazide]Iron(III) Perchlorate Trihydrate, [Fe(dapsox)(H2O)2]ClO4·3H2O

2002 • An Fe(III) Complex with the Dianionic form of 2,6-Diacetylpyridine Bis(Acylhydrazone). The Crystal Structure of [Diaqua-2′,2′′′-(2,6-PyridinediyldiEthylidyne)Dioxamohydrazide]Iron(III) Perchlorate Trihydrate, [Fe(dapsox)(H2O)2]ClO4·3H2O

Authors: Katarina Andjelkovic, Alessia Bacchi, Giancarlo Pelizzi, Dejan Jeremić, Ivana Ivanović-Burmazović

Venue: Journal of Coordination Chemistry

Type: Publication

Abstract: The title compound was prepared by a template synthesis from 2,6-diacetylpyridine, dioxamohydrazide and Fe(ClO4)3·6H2O(mol ratio 1:2:1) in MeOH/H2O(3:1) solution and its structure determined by single-crystal X-ray diffraction; triclinic, space group P1, a = 7.5186(7), b = 10.9730(9), c = 14.6110(10) A, α = 95.866(1), β = 100.252(1), γ = 92.895(1), z = 2. The polydentate ligand is coordinated as a dianionic pentadentate while water molecules occupy apical positions in the structure. This is the first example of a monomeric, pentagonal bipyr... (read more)

Topics: Crystallography Stereochemistry

DOI: 10.1080/0095897021000058600

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