BIP! Finder - DNA Intercalating Near-Infrared Luminescent Lanthanide Complexes Containing Dipyrido[3,2-a:2′,3′-c]phenazine (dppz) Ligands: Synthesis, Crystal Structures, Stability, Luminescence Properties and CT-DNA Interaction

2020 • DNA Intercalating Near-Infrared Luminescent Lanthanide Complexes Containing Dipyrido[3,2-a:2′,3′-c]phenazine (dppz) Ligands: Synthesis, Crystal Structures, Stability, Luminescence Properties and CT-DNA Interaction

Authors: Aleksandar Savić; Anna M. Kaczmarek; Rik Van Deun; Kristof Van Hecke

Venue: Molecules

Type: Publication

Abstract: In order to create near-infrared (NIR) luminescent lanthanide complexes suitable for DNA-interaction, novel lanthanide dppz complexes with general formula [Ln(NO3)3(dppz)2] (Ln = Nd3+, Er3+ and Yb3+; dppz = dipyrido[3,2-a:2′,3′-c]phenazine) were synthesized, characterized and their luminescence properties were investigated. In addition, analogous compounds with other lanthanide ions (Ln = Ce3+, Pr3+, Sm3+, Eu3+, Tb3+, Dy3+, Ho3+, Tm3+, Lu3+) were prepared. All complexes were characterized by IR spectroscopy and elemental analysis. Single-cr... (read more)

Impact: 8.2232985E-9 2.8403915E-9 9 4 / Attention: 0 63

Topics: Lanthanide and Transition Metal Complexes Metal complexes synthesis and properties Magnetism in coordination complexes

Reproducibility readiness: D

PubMed Id: 33203056

External links: OpenAIRE

Related works: Dataset 8

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