BIP! Finder - Structural diversity of isothiocyanato Cd(II) and Zn(II) Girard’s T hydrazone complexes in solution and solid state: effect of H-bonding on coordination number and supramolecular assembly of Cd(II) complex in solid state

2018 • Structural diversity of isothiocyanato Cd(II) and Zn(II) Girard’s T hydrazone complexes in solution and solid state: effect of H-bonding on coordination number and supramolecular assembly of Cd(II) complex in solid state

Authors: Božidar Čobeljić, Andrej Pevec, Stepan Stepanović, Milica R. Milenković, Iztok Turel, Maja Gruden, Dušanka Radanović, Katarina Anđelković

Venue: Structural Chemistry

Type: Publication

Abstract: The isothiocyanato Zn(II) complex (1) and mixed isothiocyanato/thiocyanato Cd(II) complex (2) with the condensation product of 2-acetylpyridine and trimethylammoniumacetohydrazide chloride (Girard’s T reagent) (HLCl) were investigated both experimentally and theoretically. The crystal structures of both complexes showed tridentate N2O coordination of hydrazine ligand. In complex 1 square-pyramidal coordination surrounding of Zn(II) consists of deprotonated hydrazone ligand and two isothiocyanato ligands, while in octahedral Cd(II) complex lig... (read more)

Topics: Crystallography Stereochemistry

DOI: 10.1007/s11224-018-1155-8

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External links: Crossref OpenAIRE

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