2003 • Structural characterization and conformational analysis of (aqua)(ethylenediamine-N,N,N′-triacetato)chromium(III) monohydrate complex. Crystal structure of the cis-equatorial isomer of [Cr(ed3a)(H2O)]·H2O
Authors: Sonja Grubišić, Maja Gruden-Pavlović, Sumio Kaizaki, Svetozar R. Niketić, Narumi Sakagami-Yoshida
Venue: Inorganic Chemistry Communications
Type: Publication
Abstract: The structure of the cis-equatorial isomer of [Cr(ed3a)(H2O)] .H2O (ed3a = ethylenediamine-N, N, N'-triacetate ion) was determined by X-ray diffraction method. The complex crystallizes in the monoclinic space group P2(1)/n, a = 7.004(l) Angstrom, b = 15.958(2) Angstrom, c = 11.046(l) Angstrom, beta = 97.16(l)degrees , and Z = 4. Conformational analysis of the three possible geometrical isomers, trans(H2O,N'), trans(H2O,N-H), and trans(H2O,O) of [Cr(ed3a)(H2O)] moiety, performed using the consistent force field (CFF) program with the recently de... (read more)
Topics:  Crystallography Stereochemistry
DOI: 10.1016/s1387-7003(03)00220-x
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