2006 • Synthesis and characterization of Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(selenosemicarbazone). Crystal structure of a Ni(II) complex with a modified 2,6-diacetylpyridine-bis(selenosemicarbazone)
Authors: Todorović, Tamara, Bacchi, Alessia, Pelizzi, Giancarlo, Juranic, Nenad O., Sladić, Dušan, Brčeski, Ilija, Anđelković, Katarina K.
Venue: Inorganic Chemistry Communications
Type: Publication
Abstract: A novel ligand 2,6-diacetylpyridine-bis(selenosemicarbazone) was synthesized and coordinated with Zn(II), Cd(II) and Ni(II). With Zn(II) and Cd(II), the bideprotonated ligand was coordinated as a quinquedentate in trigonal bipyramidal geometry. With Ni(II) during coordination the ligand was modified by elimination of hydrogen selenide and the product was coordinated as a quadridentate forming a square planar complex, the structure of which was determined by X-ray analysis. (C) 2006 Elsevier B.V. All rights reserved.
Topics:  Crystallography Stereochemistry
DOI: 10.1016/j.inoche.2006.05.011
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